Yes, there are two solutions.
x=2 is, as you said, one solution. Newton's Method can be used to find the other one.
2x=exln(2), (d/dx)2x=2xexln(2).
Let f(x)=x+2-2x, f'(x)=1-2xln(2).
xn+1=xn-f(xn)/f'(xn). Let x0=0.
x1=-1/(1-ln(2))=-3.258...
x2=-1.789...
x3=-1.690...
x4=-1.69009...
x5=-1.690093068...
x6=-1.69009306762...
So the two solutions are 2 (as expected) and -1.6901 approx.
Newton's Method can be used to find x=2 if we start with x0=1.
The graph below shows why there are two solutions (x-intercepts):
GRAPH OF x+2-2x

Courtesy of Desmos.com.